Because the time it takes to convert biological materials to fossil fuels is substantially longer than the time it takes for its in the atmosphere, which attained a maximum in 1963 of almost twice what it had been before the testing began.
Measurement of radiocarbon was originally done by beta-counting devices, which counted the amount of beta radiation emitted by decaying atoms in the sample and not just the few that happen to decay during the measurements; it can therefore be used with much smaller samples (as small as individual plant seeds), and gives results much more quickly.
In 1939, Martin Kamen and Samuel Ruben of the Radiation Laboratory at Berkeley began experiments to determine if any of the elements common in organic matter had isotopes with half-lives long enough to be of value in biomedical research.
Over time, however, discrepancies began to appear between the known chronology for the oldest Egyptian dynasties and the radiocarbon dates of Egyptian artefacts.
The method was developed by Willard Libby in the late 1940s and soon became a standard tool for archaeologists.
Libby received the Nobel Prize in Chemistry for his work in 1960.
Libby and James Arnold proceeded to test the radiocarbon dating theory by analyzing samples with known ages.
For example, two samples taken from the tombs of two Egyptian kings, Zoser and Sneferu, independently dated to 2625 BC plus or minus 75 years, were dated by radiocarbon measurement to an average of 2800 BC plus or minus 250 years. Carbon dioxide produced in this way diffuses in the atmosphere, is dissolved in the ocean, and is taken up by plants via photosynthesis.